Hefei National Laboratory for Physical Sciences at the Microscale, University of Science & Technology of China, Hefei, Anhui 230026 (P.R. China).
Angew Chem Int Ed Engl. 2013 Sep 27;52(40):10569-72. doi: 10.1002/anie.201305530. Epub 2013 Aug 15.
The thinner the better: SnO2 sheets that are five atomic layers thick are an efficient catalyst for the oxidation of CO. These sheets, which have 40% surface atom occupancy and are fabricated by a scalable ethylenediamine-assisted pathway, show remarkably improved catalytic performances compared to other SnO2 species, with the apparent activation energy lowered to 59.2 kJ mol(-1) and the full-conversion-temperature lowered to 250 °C.
厚度为五个原子层的 SnO2 薄片是 CO 氧化的高效催化剂。这些薄片通过可扩展的乙二胺辅助途径制备,具有 40%的表面原子占有率,与其他 SnO2 物质相比,表现出显著改善的催化性能,表观活化能降低至 59.2 kJ mol(-1),完全转化温度降低至 250 °C。