对映选择性 Ullmann 醚偶联反应：（-）-杨梅酮、（-）-羽扇豆醇、（+）-galeon 和（+）-紫檀芪的合成。
Enantioselective Ullmann ether couplings: syntheses of (-)-myricatomentogenin, (-)-jugcathanin, (+)-galeon, and (+)-pterocarine.
机构信息
Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, Oregon 97331, USA.
出版信息
Org Lett. 2013 Sep 6;15(17):4540-3. doi: 10.1021/ol402096k. Epub 2013 Aug 15.
PMID:23947738
Abstract
The first enantioselective Ullmann cross-coupling reactions to prepare diaryl ethers are reported. The reactions were used to prepare the diarylether heptanoid natural products (-)-myricatomentogenin, (-)-jugcathanin, (+)-galeon, and (+)-pterocarine.
摘要
首次报道了用于制备二芳基醚类天然产物（-）-myricatomentogenin、（-）-jugcathanin、（+）-galeon 和（+）-pterocarine 的对映选择性 Ullmann 交叉偶联反应。
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