College of Environmental Science and Engineering, Hunan University, Changsha, China.
PLoS One. 2013 Aug 8;8(8):e71176. doi: 10.1371/journal.pone.0071176. eCollection 2013.
Xiawanggang River region is considered to be one of the most polluted areas in China due to its huge amount discharge of pollutants and accumulation for years. As it is one branch of Xiang River and the area downstream is Changsha city, the capital of Hunan Province, the ecological niche of Xiawangang River is very important. The pollution treatment in this area was emphasized in the Twelfth Five-Year Plan of Chinese government for Xiang River Water Environmental Pollution Control. In order to assess the heavy metal pollution and provide the base information in this region for The Twelfth Five-Year Plan, contents and fractions of four heavy metals (Cd, Cu, Pb and Zn) covering both sediments and soils were analyzed to study their contamination state. Three different indexes were applied to assess the pollution extent. The results showed this area was severely polluted by the four heavy metals, and the total concentrations exceeded the Chinese environmental quality standard for soil, grade III, especially for Cd. Moreover, Cd, rated as being in high risk, had a high mobility as its great contents of exchangeable and carbonates fractions in spite of its relative low content. Regression analysis revealed clay could well explain the regression equation for Cd, Cu and Zn while pH and sand could significantly interpret the regression equation for Pb. Moreover, there was a significant correlation between Non-residual fraction and I(geo) for all the four metals. Correlation analysis showed four metals maybe had similar pollution sources.
下望岗河流域是中国污染最严重的地区之一,其大量污染物的排放和多年来的积累导致了这一情况。由于它是湘江的一个支流,且该地区的下游是湖南省的省会长沙,因此下望岗河流域的生态位非常重要。中国政府在《湘江流域水污染防治“十二五”规划》中强调了该地区的污染治理。为了评估重金属污染状况,并为该地区的“十二五”规划提供基础信息,对覆盖沉积物和土壤的四种重金属(Cd、Cu、Pb 和 Zn)的含量和形态进行了分析,以研究其污染状况。采用了三种不同的指标来评估污染程度。结果表明,该地区受四种重金属的严重污染,总浓度超过了中国土壤环境质量标准(三级),尤其是 Cd。此外,尽管 Cd 的含量相对较低,但因其可交换态和碳酸盐态含量较高,被评为高风险,具有较高的迁移性。回归分析表明,粘土可以很好地解释 Cd、Cu 和 Zn 的回归方程,而 pH 值和砂可以很好地解释 Pb 的回归方程。此外,所有四种金属的非残渣部分与 I(geo)之间存在显著相关性。相关分析表明,四种金属可能具有相似的污染源。