Department of Chemical Engineering, Chungnam National University, Daejeon, 305-764, Republic of Korea.
Adv Mater. 2013 Nov 20;25(43):6250-5. doi: 10.1002/adma.201302710. Epub 2013 Aug 21.
Hierarchical hollow spheres of Fe2 O3 @polyaniline are fabricated by template-free synthesis of iron oxides followed by a post in- and exterior construction. A combination of large surface area with porous structure, fast ion/electron transport, and mechanical integrity renders this material attractive as a lithium-ion anode, showing superior rate capability and cycling performance.
通过无模板合成氧化铁,再进行内外构建,制备出了具有分级中空结构的 Fe2 O3 @聚苯胺。这种材料具有大的比表面积和多孔结构、快速的离子/电子传输以及机械完整性,因此作为锂离子阳极具有吸引力,表现出优异的倍率性能和循环性能。