自组装主体空腔精确识别六氟硅酸根：两个配位键和十二个 CH···F 键的协同作用。
Self-assembly cavitand precisely recognizing hexafluorosilicate: a concerted action of two coordination and twelve CH···F bonds.
机构信息
Inorganic Chemistry Dpt, Taras Shevchenko National University of Kyiv, Volodymyrska Str. 64/13, Kyiv 01601, Ukraine.
出版信息
Chem Commun (Camb). 2013 Oct 11;49(79):9018-20. doi: 10.1039/c3cc45271a.
PMID:23970336
Abstract
Bis-pyridazine tectons support the structure of metallosupramolecular cavitand Cu2L4(4+), which is capable of selective encapsulation of SiF6(2-) anions by a set of multiple host-guest interactions.
摘要
双嘧啶 tectons 支撑着金属超分子穴 Cavitand Cu2L4(4+) 的结构，该结构能够通过一系列多重主客体相互作用选择性地包合 SiF6(2-) 阴离子。
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