DPMC-MaNEP, University of Geneva , 24 Quai Ernest-Ansermet, 1211 Geneva 4, Switzerland.
Nano Lett. 2013 Sep 11;13(9):4527-31. doi: 10.1021/nl4024808. Epub 2013 Aug 28.
Carbon nanotubes used as conductive atomic force microscopy probes are expected to withstand extremely high currents. However, in existing prototypes, significant self-heating results in rapid degradation of the nanotube probe. Here, we investigate an alternative probe design, fabricated by dielectric encapsulation of multiwalled carbon nanotubes, which can support unexpectedly high currents with extreme stability. We show that the dielectric coating acts as a reservoir for Joule heat removal, and as a chemical barrier against thermal oxidation, greatly enhancing transport properties. In contact with Au surfaces, these probes can carry currents of 0.12 mA at a power of 1.5 mW and show no measurable change in resistance at current densities of 10(12) A/m(2) over a time scale of 10(3) s. Our observations are in good agreement with theoretical modeling and exact numerical calculations, demonstrating that the enhanced transport characteristics of such probes are governed by their more effective heat removal mechanisms.
用作导电原子力显微镜探针的碳纳米管有望承受极高的电流。然而,在现有的原型中,显著的自热会导致纳米管探针的快速降解。在这里,我们研究了一种替代的探针设计,通过多壁碳纳米管的介电封装来制造,这种设计可以以极高的稳定性支持极高的电流。我们表明,介电涂层作为焦耳热去除的储层,以及对热氧化的化学屏障,极大地增强了传输性能。与 Au 表面接触时,这些探针可以在 1.5 mW 的功率下承载 0.12 mA 的电流,并且在 10(12) A/m(2)的电流密度下,在 10(3) s 的时间尺度内,电阻没有可测量的变化。我们的观察结果与理论模型和精确数值计算非常吻合,表明这种探针增强的传输特性受其更有效的热去除机制的控制。