通过分子内氧化偶联全合成双苄基二苯并呋喃紫衫素A
Total synthesis of bisbibenzyl dibenzofuran asterelin A via intramolecular oxidative coupling.
作者信息
Makino Kosho, Harada Kenichi, Kubo Miwa, Hioki Hideaki, Fukuyama Yoshiyasu
机构信息
Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Yamashiro-cho, Tokushima 770-8514, Japan.
出版信息
Nat Prod Commun. 2013 Jul;8(7):915-8.
PMID:23980423
Abstract
Total synthesis of asterelin A was accomplished by applying intramolecular Suzuki-Miyaura and oxidative couplings to the formation of an 18-membered macrocyclic ring and a dibenzofuran, respectively.
摘要
通过分别将分子内铃木-宫浦反应和氧化偶联反应应用于18元大环和二苯并呋喃的形成，完成了紫穗杉酯A的全合成。
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