末端烯烃的不对称二硼化反应与铑催化剂及随后的氧化反应：手性 1,2-二醇的对映选择性合成。
Asymmetric diboration of terminal alkenes with a rhodium catalyst and subsequent oxidation: enantioselective synthesis of optically active 1,2-diols.
机构信息
Department of Applied Chemistry, Graduated School of Engineering, Nagoya University, Chikusa, Nagoya, 464-8603 (Japan) http://www.apchem.nagoya-u.ac.jp/06-II-1/nisilab/index.html.
出版信息
Angew Chem Int Ed Engl. 2013 Oct 11;52(42):11011-5. doi: 10.1002/anie.201305181. Epub 2013 Sep 2.
PMID:24000239
Abstract
Pin it down: A highly enantioselective diboration of terminal alkenes with chiral 1 and bis(pinacolato)diboron (B2 pin2 ) was realized. Subsequent oxidation of the diboron adducts with sodium peroxoborate readily gave the corresponding optically active 1,2-diols in high yields and high enantioselectivities.
摘要
钉住它
实现了末端烯烃与手性 1 和双(频哪醇)二硼（B2 pin2）的高对映选择性二硼化。随后用过硼酸钠氧化二硼加合物，很容易以高收率和高对映选择性得到相应的光学活性 1,2-二醇。
Zotero 插件