双膦氧化物的高效不对称 Heck 反应催化剂。
Highly active catalysts of bisphosphine oxides for asymmetric Heck reaction.
机构信息
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore637371.
出版信息
Chem Commun (Camb). 2013 Oct 21;49(82):9425-7. doi: 10.1039/c3cc45233f.
PMID:24005808
Abstract
Bisphosphine oxides formed highly active asymmetric Heck catalysts, which were applied in asymmetric synthesis of pharmacologically active azacycles. Olefin insertion proceeded via cis pathways, different from P,N-ligands.
摘要
双膦氧化物形成了高活性的不对称 Heck 催化剂，该催化剂被应用于具有药理活性的氮杂环的不对称合成中。烯烃的插入通过顺式途径进行，与 P,N-配体不同。
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