硼酸催化硅氢化还原选择性还原酰胺为胺。
Selective reduction of amides to amines by boronic acid catalyzed hydrosilylation.
机构信息
Leibniz-Institut für Katalyse e.V. Albert-Einstein-Strasse 29a, 18059 Rostock (Germany) http://www.catalysis.de.
出版信息
Angew Chem Int Ed Engl. 2013 Oct 25;52(44):11577-80. doi: 10.1002/anie.201304495. Epub 2013 Sep 6.
PMID:24014044
Abstract
Not a 'B'ore! Benzothiophene-based boronic acids catalyze the reduction of tertiary, secondary, and primary amides in the presence of a hydrosilane. The reaction demonstrates good functional-group tolerance.
摘要
并非“无聊”！苯并噻吩基硼酸可在硅烷存在下催化叔、仲、伯酰胺的还原。该反应具有良好的官能团耐受性。
Zotero 插件