Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871 (China).
Angew Chem Int Ed Engl. 2013 Oct 25;52(44):11581-4. doi: 10.1002/anie.201304579. Epub 2013 Sep 6.
Sandmeyer-type stannylation: Stille coupling is one of the most powerful coupling reactions for CC bond formation, whereas there are only limited methods to access aryl stannane compounds. A mild stannylation process based on a Sandmeyer-type transformation using aromatic amines as the starting materials is described. DCE: 1,2-dichloroethane.
Sandmeyer 型锡化反应：Stille 偶联反应是形成 CC 键最有效的偶联反应之一，而用于制备芳基锡烷化合物的方法却很有限。本文描述了一种温和的锡化方法，基于 Sandmeyer 型转化，以芳胺作为起始原料。DCE：1,2-二氯乙烷。
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