Qiu Di, Wang Shuai, Tang Shengbo, Meng He, Jin Liang, Mo Fanyang, Zhang Yan, Wang Jianbo
Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University , Beijing 100871, China.
J Org Chem. 2014 Mar 7;79(5):1979-88. doi: 10.1021/jo402618r. Epub 2014 Feb 20.
A synthetic method based on Sandmeyer-type reactions to access both tin- and boron-substituted arenes from nitroaniline derivatives is described. This transformation can be applied to the synthesis of a series of functionalized trimethylstannyl arylboronates. In addition, the chemoselective reaction of the Stille and Suzuki-Miyaura cross-coupling reactions is explored, and a series of m- and p-terphenyl derivatives have been synthesized by conducting consecutive one-pot Stille and Suzuki-Miyaura cross-coupling reactions.
描述了一种基于桑德迈尔型反应从硝基苯胺衍生物制备锡取代和硼取代芳烃的合成方法。该转化可应用于一系列官能化三甲基甲锡烷基芳基硼酸酯的合成。此外，还探索了施蒂勒反应和铃木-宫浦交叉偶联反应的化学选择性反应，并通过连续的一锅法施蒂勒反应和铃木-宫浦交叉偶联反应合成了一系列间位和对位三联苯衍生物。
