Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University , Nishikyo-ku, Katsura, Kyoto 615-8510, Japan.
Inorg Chem. 2013 Oct 7;52(19):10735-7. doi: 10.1021/ic401924d. Epub 2013 Sep 9.
Herein, we report new porous coordination polymers (PCPs) via a facile synthetic approach called "in situ generation of functionality in the ligand". Upon a synthetic process of PCPs, a neutral (-CH2OH) or a cationic functionality (-CH2-4,4'-bipyridine) was generated on a isophthalate ligand from a reactive haloalkane (-CH2Br) moiety, affording two new PCPs. The PCPs have two-dimensional layered structures with large potential solvent-accessible voids for CO2 adsorption.
在此，我们通过一种称为“在配体中就地生成功能”的简便合成方法来报告新的多孔配位聚合物 (PCPs)。在 PCPs 的合成过程中，来自反应性卤代烷烃（-CH2Br）部分的间苯二甲酸配体上生成中性（-CH2OH）或阳离子功能（-CH2-4,4'-联吡啶），从而得到两种新的 PCPs。PCPs 具有二维层状结构，具有用于 CO2 吸附的大潜在溶剂可及空隙。
