二水合-{2,2'-二甲氧基-6,6'-[(1E,1'E)-丙烷-1,3-二亚基双(氮杂亚烷基)双(亚甲基)]二酚根合}镍(II)
Di-aqua-{2,2'-dimeth-oxy-6,6'-[(1E,1'E)-propane-1,3-diylbis(aza-nylyl-idene)bis-(methanylyl-idene)]diphenolato}nickel(II).
作者信息
Datta Amitabha, Machura Barbara, Huang Jui-Hsien, Sheu Shiann-Cherng
机构信息
Department of Chemistry, National Changhua University of Education, Changhua 50058, Taiwan.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 15;69(Pt 7):m399. doi: 10.1107/S1600536813016188. eCollection 2013.
In the mol-ecule of the title compound, [Ni(C19H20N2O4)(H2O)2], the central Ni(II) ion lies on a mirror plane and is surrounded by an N2O4 coordination set in the form of a distorted octa-hedron defined by the O atoms of two water mol-ecules and by two phenolic O and two imine N atoms of the tetra-dentate Schiff base ligand. In the crystal, O-H⋯O hydrogen bonds between the water mol-ecules and the phenolic and meth-oxy O atoms of neighbouring mol-ecules lead to the formation of rods propagating parallel to [100].
在标题化合物[Ni(C₁₉H₂₀N₂O₄)(H₂O)₂]的分子中，中心Ni(II)离子位于一个镜面平面上，被一个N₂O₄配位基团围绕，该配位基团呈扭曲八面体形式，由两个水分子的O原子以及四齿席夫碱配体的两个酚羟基O原子和两个亚胺N原子界定。在晶体中，水分子与相邻分子的酚羟基和甲氧基O原子之间的O—H⋯O氢键导致形成平行于[100]方向延伸的棒状结构。
Zotero 插件