• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

2,2'-{(1,1')-[乙烷-1,2-二基双(氮杂亚基)]双(亚甲基)}双(4-碘苯酚)。

2,2'-{(1,1')-[Ethane-1,2-diylbis(aza-nylyl-idene)]bis-(methanylyl-idene)}bis-(4-iodo-phenol).

作者信息

Blackwelder Lauren A, Kelley Andrea R, Balaich Gary J, Jefferies Latisha R

机构信息

Department of Chemistry, US Air Force Academy, CO, 80840, USA.

出版信息

IUCrdata. 2022 Sep 13;7(Pt 9):x220895. doi: 10.1107/S2414314622008951. eCollection 2022 Sep.

DOI:10.1107/S2414314622008951
PMID:36337458
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9635427/
Abstract

The title compound, CHINO, a di-iodo-Schiff base, crystallizes in space group with one mol-ecule per asymmetric unit. The mol-ecular structure reveals two intra-molecular O-H⋯N hydrogen bonds that give the mol-ecule a twisted structure with non-coplanar rings. In the crystal structure, the mol-ecular packing is stabilized by π-π stacking, hydrogen- and halogen-bonding (C-H⋯I; O⋯I) inter-actions.

摘要

标题化合物CHINO，一种二碘席夫碱，结晶于空间群，每个不对称单元中有一个分子。分子结构显示出两个分子内O-H⋯N氢键，使分子具有扭曲结构且环不共面。在晶体结构中，分子堆积通过π-π堆积、氢键和卤键（C-H⋯I；O⋯I）相互作用得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd3b/9635427/fed150cf5565/x-07-x220895-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd3b/9635427/e59351e7ee9a/x-07-x220895-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd3b/9635427/68a9fed1a1f4/x-07-x220895-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd3b/9635427/fed150cf5565/x-07-x220895-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd3b/9635427/e59351e7ee9a/x-07-x220895-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd3b/9635427/68a9fed1a1f4/x-07-x220895-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd3b/9635427/fed150cf5565/x-07-x220895-fig3.jpg

相似文献

1
2,2'-{(1,1')-[Ethane-1,2-diylbis(aza-nylyl-idene)]bis-(methanylyl-idene)}bis-(4-iodo-phenol).2,2'-{(1,1')-[乙烷-1,2-二基双(氮杂亚基)]双(亚甲基)}双(4-碘苯酚)。
IUCrdata. 2022 Sep 13;7(Pt 9):x220895. doi: 10.1107/S2414314622008951. eCollection 2022 Sep.
2
Crystal structure and Hirshfeld surfaces analysis of the nickel(II) complex of the Shiff base ligand 6,6'-{(1,1')-[ethane-1,2-diylbis(aza-nylyl-idene)]bis-(methanylyl-idene)}bis-[2-(tri-fluoro-meth-oxy)phenol].席夫碱配体6,6'-{(1,1')-[乙烷-1,2-二基双(氮杂萘基亚基)]双-(亚甲基)}双-[2-(三氟甲氧基)苯酚]的镍(II)配合物的晶体结构和 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2019 Feb 8;75(Pt 3):328-331. doi: 10.1107/S2056989019001919. eCollection 2019 Mar 1.
3
Crystal structure and Hirshfeld surface analysis of 2,2'-{(1,1')-[ethane-1,2-diylbis(aza-nylyl-idene)]bis-(methanylyl-idene)}bis-[4-(tri-fluoro-meth-oxy)phenol]copper(II) hydro-quinone hemisolvate.2,2'-{(1,1')-[乙烷-1,2-二基双(氮杂亚苯基)]双(亚甲基)}双-[4-(三氟甲氧基)苯酚]铜(II)对苯二酚半溶剂化物的晶体结构与 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2019 Oct 29;75(Pt 11):1729-1733. doi: 10.1107/S2056989019014294. eCollection 2019 Nov 1.
4
The crystal structures and Hirshfeld surface analysis of ','''-((1,1')-{[methyl-enebis(-oxy)]bis-(6-bromo-3,1-phenyl-ene)}bis-(methan-ylyl-idene))bis-(isonicotinohydrazide) dihydrate and ','''-((1,1')-{[butane-1,4-diylbis(-oxy)]bis-(2,1-phenyl-ene)}bis-(methan-ylyl-idene))bis-(isonicotino-hydrazide) [+ solvent].二水合物和[+溶剂]的“,'''-((1,1')-{[亚甲基双(-氧基)]双-(6-溴-3,1-亚苯基)}双-(亚甲基亚基))双-(异烟酰肼)和“,'''-((1,1')-{[丁烷-1,4-二基双(-氧基)]双-(2,1-亚苯基)}双-(亚甲基亚基))双-(异烟酰肼)的晶体结构和 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2019 Apr 18;75(Pt 5):655-661. doi: 10.1107/S2056989019005048. eCollection 2019 May 1.
5
Crystal structure and Hirshfeld surface analysis of 6,6'-((1,1')-{[1,4-phenyl-enebis(methyl-ene)]bis(aza-nylyl-idene)}bis-(methane-ylyl-idene))bis-(2-meth-oxy-phenol).6,6'-((1,1')-{[1,4-亚苯基双(亚甲基)]双(氮杂亚基)}双(亚甲基))双(2-甲氧基苯酚)的晶体结构和 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2022 Jan 1;78(Pt 1):84-87. doi: 10.1107/S2056989021013347.
6
Crystal structure of 9,9'-{(1,1')-[1,4-phenyl-enebis(aza-nylyl-idene)]bis-(methanylyl-idene)}bis-(2,3,6,7-tetra-hydro-1,5-pyrido[3,2,1-]quinolin-8-ol).9,9'-{(1,1')-[1,4-亚苯基双(氮杂亚烷基)]双(亚甲基)}双(2,3,6,7-四氢-1,5-吡啶并[3,2,1-]喹啉-8-醇)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Sep 5;72(Pt 10):1366-1369. doi: 10.1107/S205698901601344X. eCollection 2016 Oct 1.
7
Crystal structure, Hirshfeld surface analysis and anti-oxidant capacity of 2,2'-{(1,1')-[1,2-phenyl-enebis(aza-nylyl-idene)]bis-(methanylyl-idene)}bis-(5-benz-yloxy)phenol.2,2'-{(1,1')-[1,2-亚苯基双(氮亚基)]双(亚甲基)}双(5-苄氧基)苯酚的晶体结构、 Hirshfeld表面分析及抗氧化能力
Acta Crystallogr E Crystallogr Commun. 2018 Apr 19;74(Pt 5):682-686. doi: 10.1107/S2056989018005832. eCollection 2018 May 1.
8
Crystal structure of diethyl 2,2'-[((1E,1'E)-{[(1R,4R)-cyclo-hexane-1,4-di-yl]bis-(aza-nylyl-idene)}bis-(methanylyl-idene))bis-(1H-pyrrole-2,1-di-yl)]di-acetate.二乙基 2,2'-[((1E,1'E)-{[(1R,4R)-环己烷-1,4-二基]双-(氮杂亚烷基)}双-(亚甲基))双-(1H-吡咯-2,1-二基)]二乙酸酯的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Feb 13;71(Pt 3):o165-6. doi: 10.1107/S2056989015002674. eCollection 2015 Mar 1.
9
Di-aqua-{2,2'-dimeth-oxy-6,6'-[(1E,1'E)-propane-1,3-diylbis(aza-nylyl-idene)bis-(methanylyl-idene)]diphenolato}nickel(II).二水合-{2,2'-二甲氧基-6,6'-[(1E,1'E)-丙烷-1,3-二亚基双(氮杂亚烷基)双(亚甲基)]二酚根合}镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 15;69(Pt 7):m399. doi: 10.1107/S1600536813016188. eCollection 2013.
10
6,6'-[(1,1')-Oxybis(4,1-phenyl-ene)bis-(aza-nylyl-idene)bis-(methanylyl-idene)]bis-(2-methyl-phenol): supra-molecular assemblies in two dimensions mediated by weak C-H⋯N, C-H⋯O and C-H⋯π inter-actions.6,6'-[(1,1')-氧代双(4,1-亚苯基)双(氮杂亚烷基)双(亚甲基)]双(2-甲基苯酚)：由弱C-H⋯N、C-H⋯O和C-H⋯π相互作用介导的二维超分子组装体
Acta Crystallogr E Crystallogr Commun. 2018 Apr 24;74(Pt 5):687-690. doi: 10.1107/S2056989018005959. eCollection 2018 May 1.

本文引用的文献

1
A Review on the Antimicrobial Activity of Schiff Bases: Data Collection and Recent Studies.席夫碱抗菌活性综述：数据收集与近期研究
Antibiotics (Basel). 2022 Feb 1;11(2):191. doi: 10.3390/antibiotics11020191.
2
Water-Soluble Sulfonate Schiff-Base Ligands as Fluorescent Detectors for Metal Ions in Drinking Water and Biological Systems.水溶性磺酸盐席夫碱配体作为饮用水和生物系统中金属离子的荧光探测器
ACS Omega. 2019 Feb 8;4(2):2874-2882. doi: 10.1021/acsomega.8b02750. eCollection 2019 Feb 28.
3
1H-NMR as a structural and analytical tool of intra- and intermolecular hydrogen bonds of phenol-containing natural products and model compounds.
1H-NMR作为含酚天然产物和模型化合物分子内和分子间氢键的结构分析工具。
Molecules. 2014 Sep 2;19(9):13643-82. doi: 10.3390/molecules190913643.