2,2'-{(1,1')-[乙烷-1,2-二基双(氮杂亚基)]双(亚甲基)}双(4-碘苯酚)。
2,2'-{(1,1')-[Ethane-1,2-diylbis(aza-nylyl-idene)]bis-(methanylyl-idene)}bis-(4-iodo-phenol).
作者信息
Blackwelder Lauren A, Kelley Andrea R, Balaich Gary J, Jefferies Latisha R
机构信息
Department of Chemistry, US Air Force Academy, CO, 80840, USA.
出版信息
IUCrdata. 2022 Sep 13;7(Pt 9):x220895. doi: 10.1107/S2414314622008951. eCollection 2022 Sep.
Abstract
The title compound, CHINO, a di-iodo-Schiff base, crystallizes in space group with one mol-ecule per asymmetric unit. The mol-ecular structure reveals two intra-molecular O-H⋯N hydrogen bonds that give the mol-ecule a twisted structure with non-coplanar rings. In the crystal structure, the mol-ecular packing is stabilized by π-π stacking, hydrogen- and halogen-bonding (C-H⋯I; O⋯I) inter-actions.
摘要
标题化合物CHINO，一种二碘席夫碱，结晶于空间群，每个不对称单元中有一个分子。分子结构显示出两个分子内O-H⋯N氢键，使分子具有扭曲结构且环不共面。在晶体结构中，分子堆积通过π-π堆积、氢键和卤键（C-H⋯I；O⋯I）相互作用得以稳定。
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