• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

顺式 - 双（O - 甲基 - 二硫代碳酸根合 - κ(2) S,S'）双（三苯基膦 - κP）钌（II）

cis-Bis(O-methyl-dithio-carbonato-κ(2) S,S')bis-(tri-phenyl-phosphane-κP)ruthenium(II).

作者信息

Valerio-Cárdenas Cintya, Hernández-Ortega Simón, Reyes-Martínez Reyna, Morales-Morales David

机构信息

Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México, D.F., 04510, Mexico.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 22;69(Pt 7):m408-9. doi: 10.1107/S1600536813016735. eCollection 2013.

DOI:10.1107/S1600536813016735
PMID:24046578
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3772435/
Abstract

In the title compound, [Ru(CH3OCS2)2(C18H15P)2], the Ru(II) atom is in a distorted octa-hedral coordination by two xanthate anions (CH3OCS2) and two tri-phenyl-phosphane (PPh3) ligands. Both bidentate xanthate ligands coordinate the Ru(II) atom with two slightly different Ru-S bond lengths but with virtually equal bite angles [71.57 (4) and 71.58 (3)°]. The packing of the complexes is assured by C-H⋯O and C-H⋯π inter-actions.

摘要

在标题化合物[Ru(CH₃OCS₂)₂(C₁₈H₁₅P)₂]中，Ru(II)原子通过两个黄原酸根阴离子(CH₃OCS₂)和两个三苯基膦(PPh₃)配体处于扭曲的八面体配位环境中。两个双齿黄原酸根配体与Ru(II)原子配位，形成的Ru - S键长略有不同，但咬角几乎相等[71.57 (4) 和71.58 (3)°]。配合物的堆积通过C - H⋯O和C - H⋯π相互作用得以保证。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/3772435/9bdbd1bfdd37/e-69-0m408-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/3772435/7c475256b58b/e-69-0m408-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/3772435/9bdbd1bfdd37/e-69-0m408-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/3772435/7c475256b58b/e-69-0m408-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3b3/3772435/9bdbd1bfdd37/e-69-0m408-fig2.jpg

相似文献

1
cis-Bis(O-methyl-dithio-carbonato-κ(2) S,S')bis-(tri-phenyl-phosphane-κP)ruthenium(II).顺式 - 双（O - 甲基 - 二硫代碳酸根合 - κ(2) S,S'）双（三苯基膦 - κP）钌（II）
Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 22;69(Pt 7):m408-9. doi: 10.1107/S1600536813016735. eCollection 2013.
2
Aqua-carbon-yl(ferrocenyldi-thio-phos-phon-ato-κ(2) S,S')bis-(tri-phenyl-phosphane-κP)ruthenium(II) dichloromethane mono-solvate.二氯甲烷单溶剂合物-羰基（二硫代磷酸根合二茂铁-κ(2) S,S'）双（三苯基膦-κP）钌（II）
Acta Crystallogr Sect E Struct Rep Online. 2013 May 31;69(Pt 6):m343. doi: 10.1107/S1600536813014311. Print 2013 Jun 1.
3
Crystal structure of bis-[(acetato-κO)(imidazolidine-2-thione-κS)bis-(tri-phenyl-phosphane-κP)silver(I)] di-μ-imidazol-idine-2-thione-κ(4) S:S-bis-[(imidazol-id-ine-2-thione-κS)bis-(tri-phenyl-phosphane-κP)silver(I)] di-acetate aceto-nitrile disolvate tetra-hydrate.双-[(乙酸根-κO)(咪唑烷-2-硫酮-κS)双-(三苯基膦-κP)银(I)]二-μ-咪唑烷-2-硫酮-κ(4)S:S-双-[(咪唑烷-2-硫酮-κS)双-(三苯基膦-κP)银(I)]二乙酸乙腈溶剂合物四水合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Mar 4;72(Pt 4):444-7. doi: 10.1107/S205698901600308X. eCollection 2016 Apr 1.
4
Bis(methyl xanthato)-κS;κS:S'-(triphenyl-phosphane-κP)palladium(II).双（黄原酸甲酯）-κS；κS:S'-（三苯基膦-κP）钯（II）
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1518. doi: 10.1107/S1600536811040487. Epub 2011 Oct 12.
5
Tris(aceto-nitrile-κN)dichlorido(tri-phenyl-phosphane-κP)ruthenium(II) aceto-nitrile monosolvate.三（乙腈 - κN）二氯（三苯基膦 - κP）钌（II）乙腈单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2013 May 25;69(Pt 6):m340. doi: 10.1107/S1600536813014128. Print 2013 Jun 1.
6
Carbonyl-bis-(triphenyl-phosphane-κP)(η(2)-1-vinyl-pyrrolidin-2-one-κO)ruthenium(0).羰基-双-（三苯基膦-κP）（η(2)-1-乙烯基-吡咯烷-2-酮-κO）钌(0)
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m608. doi: 10.1107/S1600536812014766. Epub 2012 Apr 18.
7
-Bis[bis-(di-phenyl-phosphan-yl)methane-κ,']di-chlorido-ruthenium(II): a triclinic polymorph.-双[双（二苯基膦基）甲烷-κ']二氯钌（II）：一种三斜多晶型物。
IUCrdata. 2023 Nov 14;8(Pt 11):x230984. doi: 10.1107/S2414314623009847. eCollection 2023 Nov.
8
Crystal structure of [,-bis-(di-phenyl-phospho-ro-thio-yl)amidato-κ,']bis-(tri-phenyl-phosphane-κ)copper(I) di-chloro-methane monosolvate.[α,α-双（二苯基磷酰硫基）氨基甲酸根-κ²S,N]双（三苯基膦-κP）铜（I）二氯甲烷单溶剂合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Jul 4;73(Pt 8):1105-1107. doi: 10.1107/S2056989017009380. eCollection 2017 Jul 1.
9
Crystal structure of [1-(3-eth-oxy-2-oxido-benzyl-idene-κO (2))-4-phenyl-thio-semicarbazidato-κ(2) N (1),S](tri-phenylphosphane-κP)nickel(II).[1-(3-乙氧基-2-氧化苯基亚甲基-κO(2))-4-苯基硫代氨基脲-κ(2)N(1),S](三苯基膦-κP)镍(II)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Nov 21;71(Pt 12):m230-1. doi: 10.1107/S2056989015021660. eCollection 2015 Dec 1.
10
Crystal structure of bis-(3-bromo-pyridine-κN)bis-(O-ethyl di-thio-carbonato-κ(2) S,S')nickel(II).双（3-溴吡啶-κN）双（O-乙基二硫代碳酸酯-κ(2) S,S'）镍（II）的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jan 1;71(Pt 1):m12-3. doi: 10.1107/S2056989014027339.

本文引用的文献

1
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Syntheses, structural determinations of [Ru(ROCS2)2(PPh3)2](+/0) pairs, and kinetic analyses of thermal reactions involving transient trans-[Ru(iPrOCS2)2(PPh3)2] species (ROCS2(-) = ethyl- or isopropyldithiocarbonate and PPh3 = triphenylphosphine).
[Ru(ROCS2)2(PPh3)2](+/0)对的合成、结构测定以及涉及瞬态反式-[Ru(iPrOCS2)2(PPh3)2]物种的热反应动力学分析（ROCS2(-)=乙基或异丙基二硫代碳酸酯，PPh3=三苯基膦）。
Inorg Chem. 2006 Feb 6;45(3):1349-55. doi: 10.1021/ic051487l.