三（乙腈 - κN）二氯（三苯基膦 - κP）钌（II）乙腈单溶剂合物
Tris(aceto-nitrile-κN)dichlorido(tri-phenyl-phosphane-κP)ruthenium(II) aceto-nitrile monosolvate.
作者信息
Yin Xiao-Feng, Qin Yi, Shi Hua-Tian, Chen Qun, Zhang Qian-Feng
机构信息
Department of Applied Chemistry, School of Petrochemical Engineering, Changzhou University, Jiangsu 213164, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 May 25;69(Pt 6):m340. doi: 10.1107/S1600536813014128. Print 2013 Jun 1.
In the title complex, [RuCl2(CH3CN)3(C18H15P)]·CH3CN, the coordination geometry of the Ru(II) atom is distorted octa-hedral, defined by one P atom from a tri-phenyl-phosphane ligand, three N atoms from three aceto-nitrile ligands and two Cl atoms. The three acetronitile ligands linearly bind to the Ru(II) atom, with Ru-N-C angles of 172.6 (2), 179.9 (2) and 171.4 (2)°.
在标题配合物[RuCl2(CH3CN)3(C18H15P)]·CH3CN中，Ru(II)原子的配位几何构型为畸变八面体，由三苯基膦配体中的一个P原子、三个乙腈配体中的三个N原子和两个Cl原子确定。三个乙腈配体与Ru(II)原子线性配位，Ru-N-C键角分别为172.6 (2)°、179.9 (2)°和171.4 (2)°。
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