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反式-二氯二氨双(1H-咪唑-κN(3))镍(II)

trans-Diamminedichloridobis(1H-imidazole-κN (3))nickel(II).

作者信息

Kannan Piskala Subburaman, Ganeshraja Ayyakannu Sundaram, Rajkumar Kanniah, Anbalagan Krishnamoorthy, Subbiahpandi Arunachalatheva

机构信息

Department of Physics, S.M.K. Fomra Institute of Technology, Thaiyur, Chennai 603 103, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 22;69(Pt 7):m410. doi: 10.1107/S1600536813016747. eCollection 2013.

Abstract

The whole mol-ecule of the title compound, [NiCl2(C3H4N2)2(NH3)2], is generated by inversion symmetry. The Ni(II) ion, which is located on an inversion center, has a distorted octa-hedral coordination environment and is surrounded by two ammine N atoms and two Cl atoms in the equatorial plane, with two N atoms of two imidazole groups occupying the axial positions. The imidazole ring makes a dihedral angle of 81.78 (18)° with the Ni/N/Cl equatorial plane. In the crystal, mol-ecules are linked via N-H⋯Cl hydrogen bonds and C-H⋯π inter-actions, forming a three-dimensional network.

摘要

标题化合物[NiCl₂(C₃H₄N₂)₂(NH₃)₂]的整个分子由反演对称性生成。位于反演中心的Ni(II)离子具有扭曲的八面体配位环境,在赤道平面上被两个氨N原子和两个Cl原子包围,两个咪唑基团的两个N原子占据轴向位置。咪唑环与Ni/N/Cl赤道平面的二面角为81.78 (18)°。在晶体中,分子通过N—H⋯Cl氢键和C—H⋯π相互作用相连,形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6037/3772436/1386b3f3786f/e-69-0m410-fig1.jpg

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