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反式-二水合-双-(1H-咪唑-4-羧酸根-κN,O)镍(II)

trans-Diaqua-bis-(1H-imidazole-4-carboxyl-ato-κN,O)nickel(II).

作者信息

Zheng Shengrun, Cai Songliang, Fan Jun, Zhang Weiguang

机构信息

School of Chemistry and Environment, South China Normal University, Guangzhou 510006, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m865. doi: 10.1107/S1600536811018824. Epub 2011 Jun 11.

DOI:10.1107/S1600536811018824
PMID:21836862
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3152087/
Abstract

In the title complex, [Ni(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center and shows a distorted octa-hedral geometry, defined by two N,O-bidentate 1H-imidazole-4-carboxyl-ate ligands in the equatorial plane and two water mol-ecules in the axial positions. Inter-molecular N-H⋯O hydrogen bonds link the complex mol-ecules into layers parallel to (10[Formula: see text]), which are further linked into a three-dimensional supra-molecular network through O-H⋯O hydrogen bonds.

摘要

在标题配合物[Ni(C₄H₃N₂O₂)₂(H₂O)₂]中，Ni(II)离子位于一个对称中心上，呈现出扭曲的八面体几何构型，由赤道平面上的两个N,O-双齿1H-咪唑-4-羧酸酯配体和轴向位置的两个水分子界定。分子间的N-H⋯O氢键将配合物分子连接成平行于(10[化学式：见原文])的层，这些层通过O-H⋯O氢键进一步连接成三维超分子网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/509b/3152087/81fe70dc261e/e-67-0m865-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/509b/3152087/059af853811b/e-67-0m865-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/509b/3152087/3a5f9e71e519/e-67-0m865-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/509b/3152087/81fe70dc261e/e-67-0m865-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/509b/3152087/059af853811b/e-67-0m865-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/509b/3152087/3a5f9e71e519/e-67-0m865-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/509b/3152087/81fe70dc261e/e-67-0m865-fig3.jpg

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