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双(μ-6-甲氧基-2-{[(3-氧化丙基)亚氨基]-甲基}苯酚根)镍(II) 甲醇单溶剂合物

Bis(μ-6-meth-oxy-2-{[(3-oxidoprop-yl)imino]-meth-yl}phenolato)nickel(II) methanol monosolvate.

作者信息

Meng Fan-Kun, Zhang Xin, Yi Hua, Zhang De-Hui, Jia Jun-Ying

机构信息

Department of Chemistry and Chemical Engineering, Daqing Normal University, Daqing, Heilongjiang 1637121, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 29;69(Pt 7):m425. doi: 10.1107/S1600536813017224. eCollection 2013.

DOI:10.1107/S1600536813017224
PMID:24046589
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3772446/
Abstract

The mol-ecular structure of the title complex, [Ni2(C11H13NO3)2]·CH3OH, contains two Ni(II) atoms and two doubly deprotonated 6-meth-oxy-2-{[(3-oxidoprop-yl)imino]-meth-yl}phenolate ligands. The Ni(II) atoms are each four-coordinated in a distorted square-planar geometry by three O atoms and one N atom derived from the phenolate ligands. The solvent mol-ecule is linked to the complex mol-ecule by two O-H⋯O hydrogen bonds.

摘要

标题配合物[Ni2(C11H13NO3)2]·CH3OH的分子结构包含两个Ni(II)原子和两个双去质子化的6-甲氧基-2-{[(3-氧化丙基)亚氨基]甲基}酚盐配体。每个Ni(II)原子通过来自酚盐配体的三个O原子和一个N原子以扭曲的平面正方形几何构型进行四配位。溶剂分子通过两个O—H⋯O氢键与配合物分子相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d567/3772446/c3ac08217956/e-69-0m425-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d567/3772446/c3ac08217956/e-69-0m425-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d567/3772446/c3ac08217956/e-69-0m425-fig1.jpg

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