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二水合双（6-甲氧基-2-{[三（羟甲基）甲基-κO]亚氨基甲基}苯酚根-κN，O）镍（II）

Bis(6-meth-oxy-2-{[tris-(hydroxy-meth-yl)methyl-κO]imino-meth-yl}phenolato-κN,O)nickel(II) dihydrate.

作者信息

Zhou Tian, Zhou Ru-Jin, An Zhe

机构信息

School of Chemistry and Life Science, Maoming University, Maoming 525000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 17;65(Pt 7):m779. doi: 10.1107/S1600536809022028.

DOI:10.1107/S1600536809022028
PMID:21582708
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969396/
Abstract

In the title compound, [Ni(C(12)H(16)NO(5))(2)]·2H(2)O, the Ni(II) atom is coordinated by four O atoms and two N atoms from the two 6-meth-oxy-2-{[tris-(hydroxy-meth-yl)meth-yl]imino-meth-yl}phenolate ligands in a distorted octa-hedral coordination geometry. O-H⋯O hydrogen bonds link the complexes and uncoordinated water mol-ecules into two-dimensional networks parallel to (001).

摘要

在标题化合物[Ni(C₁₂H₁₆NO₅)₂]·2H₂O中，Ni(II)原子由来自两个6-甲氧基-2-{[三(羟甲基)甲基]亚氨基甲基}酚盐配体的四个O原子和两个N原子配位，形成扭曲的八面体配位几何构型。O—H⋯O氢键将配合物和未配位的水分子连接成平行于(001)的二维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/964a/2969396/c37700166dd5/e-65-0m779-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/964a/2969396/cdc54ed55f13/e-65-0m779-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/964a/2969396/c37700166dd5/e-65-0m779-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/964a/2969396/cdc54ed55f13/e-65-0m779-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/964a/2969396/c37700166dd5/e-65-0m779-fig2.jpg

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本文引用的文献

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