Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University , Beijing 100871, China.
Inorg Chem. 2013 Oct 7;52(19):10741-3. doi: 10.1021/ic402022v. Epub 2013 Sep 18.
Catalytic hydrolysis of silanes mediated by chlorodicarbonylrhodium(I) dimer [RhCl(CO)2]2 to produce silanols and dihydrogen efficiently under mild conditions is reported. Second-order kinetics and activation parameters are determined by monitoring the rate of dihydrogen evolution. The mixing of [RhCl(CO)2]2 and HSiCl3 results in rapid formation of a rhodium silane σ complex.
报道了二氯羰基二铑(I) dimer [RhCl(CO)2]2 介导的硅烷的催化水解，在温和条件下高效地生成硅醇和氢气。通过监测氢气释放的速率来确定二级动力学和活化参数。[RhCl(CO)2]2 和 HSiCl3 的混合导致铑硅烷 σ 配合物的快速形成。
