通过叠氮化物与不饱和醛的催化环加成直接获得三唑-烯烃。
Direct access to triazole-olefins through catalytic cycloaddition of azides to unsaturated aldehydes.
机构信息
Department of Chemistry, National University of Singapore, Block S15, Level 5, 3 Science Drive 3, Singapore117543.
出版信息
Chem Commun (Camb). 2013 Oct 3;49(86):10187-9. doi: 10.1039/c3cc45306e.
PMID:24051502
Abstract
In situ formed dienamines as HOMO-raising dipolarophiles react with azides to afford the corresponding triazole-olefins in good to excellent yields via a catalytic inverse-electron-demand 1,3-dipolar cycloaddition process.
摘要
原位生成的二烯胺作为 HOMO 提升的偶极亲二烯体与叠氮化物反应，通过催化的逆电子需求 1,3-偶极环加成反应，以良好至优异的收率得到相应的三唑-烯烃。
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