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通过封装在沸石咪唑酯骨架纳米晶体内部稳定石墨烯量子点(GQDs)以调节光致发光。

Stabilization of graphene quantum dots (GQDs) by encapsulation inside zeolitic imidazolate framework nanocrystals for photoluminescence tuning.

机构信息

Physical/Materials Chemistry Division, CSIR-National Chemical Laboratory, Dr Homi Bhabha Road, Pune-411 008, India.

出版信息

Nanoscale. 2013 Nov 7;5(21):10556-61. doi: 10.1039/c3nr03511e. Epub 2013 Sep 19.

Abstract

Luminescent graphene quantum dots (GQDs) are encapsulated and stabilized in Zeolitic Imidazolate Framework (ZIF-8) nanocrystals. The GQDs are well confined due to the adsorption on the growing face of the ZIF-8 nanocrystals and have a profound effect on the shape of the nanocrystals from rhombic dodecahedron to spherical. Stabilizing GQDs inside the ZIF-8 nanocrystals results in tailoring of the photoluminescence emission (ca. 32 nm, bathochromic shift) of the GQD@ZIF-8 nanocrystal composite even after 3 months of aging under normal laboratory conditions. Also the water adsorption (at STP) capacity increased for the GQD@ZIF-8 composite as compared to the pristine ZIF-8.

摘要

发光石墨烯量子点(GQDs)被封装和稳定在沸石咪唑酯骨架(ZIF-8)纳米晶体中。由于 GQDs 被吸附在 ZIF-8 纳米晶体的生长面上,因此它们被很好地限制在其中,这对纳米晶体的形状从菱形十二面体到球形产生了深远的影响。将 GQDs 稳定在 ZIF-8 纳米晶体内部,即使在正常实验室条件下老化 3 个月后,也可以调整 GQD@ZIF-8 纳米晶体复合材料的光致发光发射(约 32nm,红移)。与原始 ZIF-8 相比,GQD@ZIF-8 复合材料的水吸附(在 STP 下)能力也有所提高。

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