可见光光氧化还原原子转移 Ueno-Stork 反应。
Visible light photoredox atom transfer Ueno-Stork reaction.
机构信息
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering, and Materials Science, Soochow University, 199 RenAi Road, Suzhou, Jiangsu 215123, China.
出版信息
Org Biomol Chem. 2013 Nov 7;11(41):7088-91. doi: 10.1039/c3ob41600c.
PMID:24057342
Abstract
A visible light-promoted atom transfer Ueno-Stork reaction was developed using Ir(ppy)2(dtb-bpy)PF6 as the sensitizer. 2-Iodoethyl propargyl ethers or 2-iodoethyl allyl ethers were used as the radical precursors to construct tetrahydrofuran-containing fused [6,5] and [5,5] bicyclic frameworks.
摘要
可见光促进的原子转移 Ueno-Stork 反应使用 Ir(ppy)2(dtb-bpy)PF6 作为敏化剂开发。2-碘乙基炔丙基醚或 2-碘乙基烯丙基醚被用作自由基前体，以构建含有四氢呋喃的稠合[6,5]和[5,5]双环骨架。
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