State Key Lab of Urban Water Resource and Environment, Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin 150080, China.
J Org Chem. 2012 Jul 20;77(14):6302-6. doi: 10.1021/jo300796j. Epub 2012 Jul 3.
The reductive coupling and cyclization of chalcones to generate cyclopentanol derivatives in up to 84% yield by visible light photoredox catalysis is described. This reaction involves radical anion homocoupling, monoprotonation, and intramolecular cyclization cascade.
可见光光氧化还原催化下，查尔酮还原偶联和环化，以高达 84%的收率生成环戊醇衍生物。该反应涉及自由基阴离子同偶联、单质子化和分子内环化级联。
