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基于 NiO 的纳米结构具有高效的光学和电化学性能,适用于高性能纳米流体。

NiO-based nanostructures with efficient optical and electrochemical properties for high-performance nanofluids.

机构信息

National Physical Laboratory, Council of Scientific and Industrial Research, Dr K S Krishnan Road, New Delhi, 110012, India. Department of Physics, Panjab University, Chandigarh, 160014, India.

出版信息

Nanotechnology. 2013 Oct 18;24(41):415705. doi: 10.1088/0957-4484/24/41/415705. Epub 2013 Sep 24.

Abstract

NiO nanostructures were synthesized via a simple wet chemical solution method with varying calcination temperatures. The synthesized nanostructures were characterized by XRD, TG/DSC, FT-IR and high-resolution electron microscopy techniques. The nanostructures revealed dependence of particle size, stoichiometry, optical band gap and luminescence intensity on calcination temperatures. The materials exhibited efficient electrochemical properties with decent capacitance values. Ethylene-glycol-based nanofluids of these nanoparticles registered excellent thermal conductivity enhancement of 59-69% in the room temperature region and 125% enhancement at higher temperatures (80 ° C), establishing NiO to be a top-draw contender for high-performance heat transfer fluids.

摘要

通过改变煅烧温度的简单湿化学溶液法合成了 NiO 纳米结构。通过 XRD、TG/DSC、FT-IR 和高分辨率电子显微镜技术对合成的纳米结构进行了表征。纳米结构显示出颗粒尺寸、化学计量比、光学带隙和发光强度对煅烧温度的依赖性。这些材料表现出高效的电化学性能,具有良好的电容值。这些纳米粒子的乙二醇基纳米流体在室温区域表现出优异的热导率增强,达到 59-69%,在较高温度(80°C)时增强达到 125%,这表明 NiO 是高性能传热流体的首选。

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