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基于缺顶 Dawson 多金属氧酸盐的 3d-4f 杂化 3D POMOF。

A 3d-4f heterometallic 3D POMOF based on lacunary Dawson polyoxometalates.

机构信息

Key Laboratory of Green Chemical Engineering and Technology of College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040, China.

出版信息

Dalton Trans. 2013 Dec 14;42(46):16328-33. doi: 10.1039/c3dt51983j.

DOI:10.1039/c3dt51983j
PMID:24061561
Abstract

A novel compound, Na2Ce4(H2O)22(dpdo)52·8H2O (1) (dpdo = 4,4'-bipyridine-N,N'-dioxide) with 3d-4f heterometallic 3D POMOF that can be described as a self-penetrating (4,4,6)-connected net topology, has been isolated via a stepwise method, and its magnetic and electrocatalytic properties have been investigated.

摘要

一种新型化合物 Na2Ce4(H2O)22(dpdo)52·8H2O(1)(dpdo = 4,4'-联吡啶-N,N'-二氧),具有 3d-4f 异金属 3D POMOF,可以描述为自穿透(4,4,6)连接的网络拓扑结构,通过分步方法分离出来,并研究了其磁性和电催化性质。

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