Ribeiro Ana C F, Lobo Victor M M, Sobral Abilio J F N, Soares Helder T F C, Esteso Ana R J, Esteso Miguel A
Acta Chim Slov. 2010 Jun;57(2):410-4.
Mutual diffusion coefficients (interdiffusion coefficients) have been measured for sodium fluoride in water at 298.15 K and 310.15 K at concentrations between 0.003 mol dm-3 and 0.05 mol dm-3. The diffusion coefficients were measured using a conductimetric cell. The experimental mutual diffusion coefficients are discussed on the basis of the Onsager-Fuoss model. The limiting molar conductivity of the fluoride ion in these solutions at 310.15 K has been estimated using these results.
已在298.15 K和310.15 K温度下,对浓度介于0.003 mol dm⁻³至0.05 mol dm⁻³之间的氟化钠在水中的互扩散系数(互扩散系数)进行了测量。扩散系数是使用电导池进行测量的。基于昂萨格-福斯模型对实验互扩散系数进行了讨论。利用这些结果估算了这些溶液中氟离子在310.15 K时的极限摩尔电导率。