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一种高灵敏度混合镧系金属-有机骨架自校准荧光温度计。

A highly sensitive mixed lanthanide metal-organic framework self-calibrated luminescent thermometer.

机构信息

State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University , Hangzhou 310027, China.

出版信息

J Am Chem Soc. 2013 Oct 16;135(41):15559-64. doi: 10.1021/ja407219k. Epub 2013 Oct 8.

Abstract

A new mixed lanthanide metal-organic framework thermometer Tb0.9Eu0.1PIA with the significantly high sensitivity of 3.53% per K has been realized by making use of an organic ligand, 5-(pyridin-4-yl)isophthalate, with higher triplet state energy.

摘要

一种新型的混合镧系金属有机框架温度计 Tb0.9Eu0.1PIA 已经被实现,其灵敏度高达 3.53%/K,这是通过利用具有更高三重态能量的有机配体 5-(吡啶-4-基)间苯二甲酸实现的。

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