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碘在高度稳定的金属有机骨架中的捕获:系统研究。

Capture of iodine in highly stable metal-organic frameworks: a systematic study.

机构信息

Unité de Catalyse et Chimie du Solide (UCCS) - UMR CNRS 8181, Université de Lille Nord de France, ENSCL, Bat. C7, BP 90108, 59652 Villeneuve d'Ascq, France.

出版信息

Chem Commun (Camb). 2013 Nov 11;49(87):10320-2. doi: 10.1039/c3cc43728k.

DOI:10.1039/c3cc43728k
PMID:24067882
Abstract

A series of aluminum-based metal-organic frameworks were investigated for sorption of iodine (I2) in cyclohexane. The best sorption uptake was obtained with solids decorated by electro-donor groups attached either to the organic ligand (-NH2) or the inorganic sub-network (-OH).

摘要

研究了一系列基于铝的金属有机骨架在环己烷中对碘(I2)的吸附。用修饰有供电子基团的固体(这些基团要么连接在有机配体(-NH2)上,要么连接在无机子网络(-OH)上),得到了最佳的吸附量。

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