Solventless fabrication of porous-on-porous materials.

Here we fabricate patterned porous polymer membranes on porous substrates by a combination of physical masking and chemical vapor deposition. This all-dry technique eliminates solvent-related issues and allows for the fabrication of hierarchical porous-on-porous structures with a wide range of chemical compositions and shapes. The porous polymer membranes are made by operating at unconventional processing conditions to simultaneously deposit and polymerize monomer. The solid monomer serves as a porogen and creates microstructures around which polymer forms. Membranes with thicknesses ranging from a few hundred micrometers to a millimeter are fabricated on porous paper substrates. The resolution of the patterning process and the structure of the resulting membranes are analyzed as a function of the deposition time. It was found that the patterned membranes exhibit a tapered structure and the dimensions are in good agreement with the dimensions of the mask. One potential application of these patterned polymer membranes is demonstrated for the selective separation of analytes for diagnostic applications on paper-based microfluidic devices. The ability to pattern porous-on-porous structures can be useful for the development of hierarchical membranes for water purification and gas separation, and for sensing, patterned tissue scaffolding, and other lab-on-a-chip applications.