铑催化下烯丙基乙酸酯与吲哚的合成及 C2-官能化。
Synthesis and C2-functionalization of indoles with allylic acetates under rhodium catalysis.
机构信息
School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea.
出版信息
Org Biomol Chem. 2013 Nov 14;11(42):7427-34. doi: 10.1039/c3ob41828f.
PMID:24081311
Abstract
Tandem rhodium-catalyzed oxidative allylation and annulation of acetanilides with allyl acetate to afford the corresponding indoles are described. In addition, the site-selective C2 allylation, crotylation and prenylation of indoles using allylic acetates under rhodium catalysis are reported.
摘要
串联铑催化氧化烯丙基化和芳构化乙酰苯胺与烯丙基乙酸酯，以提供相应的吲哚，被描述。此外，还报道了在铑催化下使用烯丙基乙酸酯对吲哚进行选择性 C2 烯丙基化、巴豆基化和普雷尼基化。
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