Department of Chemistry, Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QZ, United Kingdom.
Phys Rev Lett. 2013 Sep 20;111(12):128301. doi: 10.1103/PhysRevLett.111.128301. Epub 2013 Sep 17.
The dynamics of two-dimensional fluids confined within a random matrix of obstacles is investigated using both colloidal model experiments and molecular dynamics simulations. By varying fluid and matrix area fractions in the experiment, we find delocalized tracer particle dynamics at small matrix area fractions and localized motion of the tracers at high matrix area fractions. In the delocalized region, the dynamics is subdiffusive at intermediate times, and diffusive at long times, while in the localized regime, trapping in finite pockets of the matrix is observed. These observations are found to agree with the simulation of an ideal gas confined in a weakly correlated matrix. Our results show that Lorentz gas systems with soft interactions are exhibiting a smoothening of the critical dynamics and consequently a rounded delocalization-to-localization transition.
使用胶体模型实验和分子动力学模拟研究了受限在随机障碍物矩阵中的二维流体的动力学。通过在实验中改变流体和矩阵的面积分数,我们发现当矩阵面积分数较小时,示踪粒子的动力学是离域的,而当矩阵面积分数较高时,示踪粒子的运动是局域的。在离域区域,动力学在中间时间是亚扩散的,在长时间是扩散的,而在局域区域,观察到在矩阵的有限口袋中的捕获。这些观察结果与在弱相关矩阵中受限的理想气体的模拟结果一致。我们的结果表明,具有软相互作用的洛伦兹气体系统表现出临界动力学的平滑化,从而导致离域到局域的转变变得圆润。