• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

双[μ-1-(3,5-二氯吡啶-2-基)-2-(吡啶-3-基亚甲基)肼基]双[(硝酸根-κO)银(I)]乙腈溶剂合物

Bis[μ-1-(3,5-di-chloro-pyridin-2-yl)-2-(pyridin-3-yl-methyl-idene)hydrazine]bis-[(nitrato-κO)silver(I)] aceto-nitrile disolvate.

作者信息

Guo Ying, Cai Hua

机构信息

College of Science, Civil Aviation University of China, Tianjin 300300, People's Repulic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 4;69(Pt 10):m525. doi: 10.1107/S1600536813024021. eCollection 2013.

DOI:10.1107/S1600536813024021
PMID:24098162
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3790340/
Abstract

In the centrosymmetric binuclear title complex, [Ag2(NO3)2(C11H8Cl2N4)2]·2CH3CN, the Ag(I) atom is four-coordinated and exhibits a highly distorted tetrahedral coordination sphere defined by three N atoms from two 1-(3,5-di-chloro-pyridin-2-yl)-2-(pyridin-3-yl-methyl-idene)hy-drazine ligands and one O atom from a nitrate anion. Inter-molecular N-H⋯O hydrogen bonds link the complex mol-ecules, resulting in a two-dimensional supra-molecular structure parallel to (001).

摘要

在中心对称的双核标题配合物[Ag₂(NO₃)₂(C₁₁H₈Cl₂N₄)₂]·2CH₃CN中，Ag(I)原子为四配位，呈现出由两个1-(3,5-二氯吡啶-2-基)-2-(吡啶-3-基亚甲基)肼配体的三个N原子和一个硝酸根阴离子的O原子所定义的高度扭曲的四面体配位环境。分子间的N-H⋯O氢键连接着配合物分子，形成了一个平行于(001)的二维超分子结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a6/3790340/b14483556bb2/e-69-0m525-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a6/3790340/6f8074b4e4ee/e-69-0m525-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a6/3790340/b14483556bb2/e-69-0m525-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a6/3790340/6f8074b4e4ee/e-69-0m525-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7a6/3790340/b14483556bb2/e-69-0m525-fig2.jpg

相似文献

1
Bis[μ-1-(3,5-di-chloro-pyridin-2-yl)-2-(pyridin-3-yl-methyl-idene)hydrazine]bis-[(nitrato-κO)silver(I)] aceto-nitrile disolvate.双[μ-1-(3,5-二氯吡啶-2-基)-2-(吡啶-3-基亚甲基)肼基]双[(硝酸根-κO)银(I)]乙腈溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 4;69(Pt 10):m525. doi: 10.1107/S1600536813024021. eCollection 2013.
2
Silver(I) nitrate complexes of three tetra-kis-thio-ether-substituted pyrazine ligands: metal-organic chain, network and framework structures.三种四硫醚取代吡嗪配体的硝酸银（I）配合物：金属有机链、网络和骨架结构
Acta Crystallogr E Crystallogr Commun. 2017 Feb 24;73(Pt 3):434-440. doi: 10.1107/S2056989017002791. eCollection 2017 Mar 1.
3
Bis[μ-(E)-N-(pyridin-3-yl-methyl-idene)hy-droxy-amine]-κ(2) N (1):N (3);κ(2) N (3):N (1)-bis-{[(E)-N-(pyridin-3-yl-methyl-idene-κN)hy-droxy-amine]-silver(I)} dinitrate.双[μ-(E)-N-(吡啶-3-基-亚甲基)羟基胺]-κ(2) N(1):N(3);κ(2) N(3):N(1)-双-{[(E)-N-(吡啶-3-基-亚甲基-κN)羟基胺]-银(I)}二硝酸盐
Acta Crystallogr Sect E Struct Rep Online. 2012 Dec 1;68(Pt 12):m1547. doi: 10.1107/S1600536812045898. Epub 2012 Nov 28.
4
Crystal structure of bis-[(acetato-κO)(imidazolidine-2-thione-κS)bis-(tri-phenyl-phosphane-κP)silver(I)] di-μ-imidazol-idine-2-thione-κ(4) S:S-bis-[(imidazol-id-ine-2-thione-κS)bis-(tri-phenyl-phosphane-κP)silver(I)] di-acetate aceto-nitrile disolvate tetra-hydrate.双-[(乙酸根-κO)(咪唑烷-2-硫酮-κS)双-(三苯基膦-κP)银(I)]二-μ-咪唑烷-2-硫酮-κ(4)S:S-双-[(咪唑烷-2-硫酮-κS)双-(三苯基膦-κP)银(I)]二乙酸乙腈溶剂合物四水合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Mar 4;72(Pt 4):444-7. doi: 10.1107/S205698901600308X. eCollection 2016 Apr 1.
5
Bis[μ-2,5-bis-(pyridin-2-yl)-1,3,4-thia-diazole-κ(4) N (2),N (3):N (4),N (5)]bis-[(nitrato-κO)silver(I)] tetra-hydrate.二水合双[μ-2,5-双-(吡啶-2-基)-1,3,4-噻二唑-κ(4)N(2),N(3):N(4),N(5)]双-[(硝酸根-κO)银(I)]
Acta Crystallogr Sect E Struct Rep Online. 2013 May 31;69(Pt 6):m351-2. doi: 10.1107/S1600536813014578. Print 2013 Jun 1.
6
Crystal structure of an Ag inter-calation compound: -poly[[silver(I)-μ--(pyridin-3-ylmeth-yl)pyridin-3-amine-κ:'] hexa-fluorido-phosphate aceto-nitrile disolvate].一种银插层化合物的晶体结构：-聚[[银（I）-μ--（吡啶-3-基甲基）吡啶-3-胺-κ:'] 六氟磷酸乙腈溶剂化物]
Acta Crystallogr E Crystallogr Commun. 2017 Sep 25;73(Pt 10):1542-1545. doi: 10.1107/S2056989017013421. eCollection 2017 Oct 1.
7
Silver(I) nitrate two-dimensional coordination polymers of two new pyrazine-thio-phane ligands: 5,7-di-hydro-1,3-dithieno[3,4-:3',4'-]pyrazine and 3,4,8,10,11,13-hexa-hydro-1,6-bis-([1,4]di-thio-cino)[6,7-:6',7'-]pyrazine.两种新型吡嗪-硫杂环戊烷配体的硝酸银（I）二维配位聚合物：5,7-二氢-1,3-二噻吩并[3,4-:3',4'-]吡嗪和3,4,8,10,11,13-六氢-1,6-双（[1,4]二硫代环戊烯并）[6,7-:6',7'-]吡嗪
Acta Crystallogr E Crystallogr Commun. 2020 Mar 13;76(Pt 4):539-546. doi: 10.1107/S205698902000362X. eCollection 2020 Apr 1.
8
[3,3'-Dihy-droxy-3,3'-bis-(pyridin-3-yl-κN)-1,1'-(pyridine-2,6-di-yl)dipropan-1-one](nitrato-κO,O')silver(I).[3,3'-二羟基-3,3'-双-(吡啶-3-基-κN)-1,1'-(吡啶-2,6-二基)二丙烷-1-酮](硝酸根-κO,O')银(I)
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m905. doi: 10.1107/S1600536811020472. Epub 2011 Jun 11.
9
Bis[μ-N-(pyridin-2-ylmeth-yl)pyridin-3-amine-κ(2) N:N']disilver(I) bis-(perchlorate) dimethyl sulfoxide disolvate.双[μ-N-(吡啶-2-基甲基)吡啶-3-胺-κ(2) N:N']二银(I) 双(高氯酸盐) 二甲亚砜溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2013 Oct 2;69(Pt 11):m575-6. doi: 10.1107/S1600536813026585.
10
Crystal structure of aqua-(nitrato-κO)dioxido{2-[3-(pyridin-2-yl-κN)-1H-1,2,4-triazol-5-yl-κN (4)]phenolato-κO}uranium(VI) aceto-nitrile monosolvate monohydrate.水合-（硝酸根-κO）二氧化物{2-[3-（吡啶-2-基-κN）-1H-1,2,4-三唑-5-基-κN（4）]苯酚根-κO}铀（VI）乙腈单溶剂合物一水合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Jan 6;72(Pt 2):111-3. doi: 10.1107/S205698901502438X. eCollection 2016 Feb 1.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.