双（1,10-菲咯啉-κ(2) N,N'）（硫酸根-κO）锌（II）丙二醇单溶剂合物
Bis(1,10-phenanthroline-κ(2) N,N')(sulfato-κO)zinc(II) propane-1,2-diol monosolvate.
作者信息
Zhong Kai-Long
机构信息
Department of Applied Chemistry, Nanjing College of Chemical Technology, Nanjing, 210048, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 28;69(Pt 10):m561. doi: 10.1107/S160053681302610X. eCollection 2013.
In the title compound, [Zn(SO4)(C12H8N2)2]·C3H8O2, the Zn(II) ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn(II) ion lies on a twofold rotation axis. The sulfate ligand and propane-1,2-diol mol-ecules are disordered across the twofold rotation axis. The dihedral angle between the two chelating N2C2 groups is 83.26 (13)°. In the crystal, the complex mol-ecule and the propane-1,2-diol mol-ecule are connected through a pair of O-H⋯O hydrogen bonds.
在标题化合物[Zn(SO₄)(C₁₂H₈N₂)₂]·C₃H₈O₂中，Zn(II)离子处于扭曲的四方锥配位环境中，该环境由来自两个螯合的1,10 - 菲咯啉配体的四个N原子和来自一个单齿硫酸根配体的一个O原子组成。Zn(II)离子位于二重旋转轴上。硫酸根配体和1,2 - 丙二醇分子在二重旋转轴上无序分布。两个螯合的N₂C₂基团之间的二面角为83.26 (13)°。在晶体中，配合物分子和1,2 - 丙二醇分子通过一对O—H⋯O氢键相连。
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