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双(1,10-菲咯啉-κ(2) N,N')(硫酸根-κ(2) O,O')钴(II)丙二醇单溶剂合物

Bis(1,10-phenanthroline-κ(2) N,N')(sulfato-κ(2) O,O')cobalt(II) propane-1,2-diol monosolvate.

作者信息

Zhong Kai-Long

机构信息

Department of Applied Chemistry, Nanjing College of Chemical Technology, Nanjing 210048, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):m26. doi: 10.1107/S1600536812049616. Epub 2012 Dec 8.

Abstract

In the title compound, [Co(SO4)(C12H8N2)2]·C3H8O2, the Co(II) atom (site symmetry 2) has a distorted octa-hedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O'-bidentate sulfate ligand, in which the S atom has site symmetry 2. The dihedral angle between the two chelating N2C2 groups is 84.46 (15)°. The complex and solvent mol-ecules are connected through O-H⋯O hydrogen bonds. The solvent mol-ecule is equally disordered over two positions and is also located on a twofold axis.

摘要

在标题化合物[Co(SO₄)(C₁₂H₈N₂)₂]·C₃H₈O₂中,Co(II)原子(位点对称性为2)具有扭曲的八面体配位结构,由来自两个螯合1,10 - 菲咯啉配体的四个N原子和来自一个O,O'-双齿硫酸根配体的两个O原子组成,其中S原子的位点对称性为2。两个螯合N₂C₂基团之间的二面角为84.46 (15)°。配合物与溶剂分子通过O—H⋯O氢键相连。溶剂分子在两个位置上无序分布且同样位于一个二重轴上。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f450/3588351/f1df7765d25e/e-69-00m26-fig1.jpg

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