Zhong Kai-Long
Department of Applied Chemistry, Nanjing College of Chemical Technology, Nanjing 210048, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):m26. doi: 10.1107/S1600536812049616. Epub 2012 Dec 8.
In the title compound, [Co(SO4)(C12H8N2)2]·C3H8O2, the Co(II) atom (site symmetry 2) has a distorted octa-hedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O'-bidentate sulfate ligand, in which the S atom has site symmetry 2. The dihedral angle between the two chelating N2C2 groups is 84.46 (15)°. The complex and solvent mol-ecules are connected through O-H⋯O hydrogen bonds. The solvent mol-ecule is equally disordered over two positions and is also located on a twofold axis.
在标题化合物[Co(SO₄)(C₁₂H₈N₂)₂]·C₃H₈O₂中,Co(II)原子(位点对称性为2)具有扭曲的八面体配位结构,由来自两个螯合1,10 - 菲咯啉配体的四个N原子和来自一个O,O'-双齿硫酸根配体的两个O原子组成,其中S原子的位点对称性为2。两个螯合N₂C₂基团之间的二面角为84.46 (15)°。配合物与溶剂分子通过O—H⋯O氢键相连。溶剂分子在两个位置上无序分布且同样位于一个二重轴上。