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3,3'-(苯基亚甲基)双(1H-吲哚-2-羧酸甲酯)二甲酯

Dimethyl 3,3'-(phenyl-methyl-ene)bis-(1H-indole-2-carboxyl-ate).

作者信息

Sun Hong-Shun, Li Yu-Long, Xu Ning, Xu Hong, Zhang Ji-Dong

机构信息

Chemical Engineering Department, Nanjing College of Chemical Technology, Geguan Road No. 265 Nanjing, Nanjing 210048, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 7;69(Pt 10):o1516. doi: 10.1107/S1600536813024471. eCollection 2013.

Abstract

In the title compound, C27H22N2O4, the two indole ring systems are approximately perpendicular to each other, with a dihedral angle of 84.5 (5)° between their planes; the benzene ring is twisted with respect to the two indole ring systems at angles of 78.5 (5) and 86.5 (3)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, weak C-H⋯O and C-H⋯N hydrogen bonds, and C-H⋯π inter-actions into a three-dimensional supra-molecular architecture.

摘要

在标题化合物C₂₇H₂₂N₂O₄中,两个吲哚环系统彼此大致垂直,它们的平面之间的二面角为84.5 (5)°;苯环相对于两个吲哚环系统扭转的角度分别为78.5 (5)°和86.5 (3)°。在晶体中,分子通过N-H⋯O氢键、弱C-H⋯O和C-H⋯N氢键以及C-H⋯π相互作用连接成三维超分子结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a0bc/3790385/ec40c00c534a/e-69-o1516-fig1.jpg

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