• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

3,3'-[(3-氟苯基)亚甲基]双(1-吲哚-2-羧酸乙酯)

Diethyl 3,3'-[(3-fluoro-phen-yl)methyl-ene]bis-(1-indole-2-carboxyl-ate).

作者信息

Jiang Hong, Li Yu-Long, Zhou Jin, Sun Hong-Shun, Zhang Qing-Yu, Shi Xing-Hao, Zhang Zhi-Yuan, Ling Tian

机构信息

Targeted MRI Contrast Agents Laboratory of Jiangsu Province, Nanjing Polytechnic Institute, Nanjing 210048, People's Republic of China.

College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, People's Republic of China.

出版信息

IUCrdata. 2020 Jul 10;5(Pt 7):x200912. doi: 10.1107/S2414314620009128. eCollection 2020 Jul.

DOI:10.1107/S2414314620009128
PMID:36339780
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9462259/
Abstract

In the title compound, CHFNO, the mean planes of the indole ring systems are approximately perpendicular to one another [dihedral angle = 88.3 (4)°]. The benzene ring is twisted with respect to the indole ring systems by 49.8 (5) and 77.6 (3)°. In the crystal, pairs of N-H⋯O hydrogen bonds link the mol-ecules into the inversion dimers which are further linked into supra-molecular chains propagating along the [110] direction.

摘要

在标题化合物CHFNO中，吲哚环系的平均平面彼此近似垂直[二面角 = 88.3 (4)°]。苯环相对于吲哚环系扭转了49.8 (5)°和77.6 (3)°。在晶体中，N-H⋯O氢键对将分子连接成反演二聚体，这些二聚体进一步连接成沿[110]方向延伸的超分子链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49bb/9462259/ac6379482618/x-05-x200912-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49bb/9462259/b3cd10e5ff59/x-05-x200912-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49bb/9462259/ac6379482618/x-05-x200912-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49bb/9462259/b3cd10e5ff59/x-05-x200912-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49bb/9462259/ac6379482618/x-05-x200912-fig2.jpg

相似文献

1
Diethyl 3,3'-[(3-fluoro-phen-yl)methyl-ene]bis-(1-indole-2-carboxyl-ate).3,3'-[(3-氟苯基)亚甲基]双(1-吲哚-2-羧酸乙酯)
IUCrdata. 2020 Jul 10;5(Pt 7):x200912. doi: 10.1107/S2414314620009128. eCollection 2020 Jul.
2
Crystal structure of diethyl 3,3'-[(2-fluoro-phen-yl)methyl-idene]bis-(1-indole-2-carboxyl-ate).3,3'-[(2-氟苯基)亚甲基]双(1-吲哚-2-羧酸乙酯)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Oct 31;73(Pt 11):1790-1792. doi: 10.1107/S2056989017015523. eCollection 2017 Nov 1.
3
Crystal structure of diethyl 3,3'-[(4-nitro-phen-yl)methyl-ene]bis-(1-indole-2-carboxyl-ate).3,3'-[(4-硝基苯基)亚甲基]双(1-吲哚-2-羧酸乙酯)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Nov 28;73(Pt 12):1956-1958. doi: 10.1107/S2056989017016929. eCollection 2017 Dec 1.
4
Crystal structure of dimethyl 3,3'-[(4-fluoro-phen-yl)methyl-ene]bis-(1H-indole-2-carboxyl-ate).3,3'-[(4-氟苯基)亚甲基]双(1H-吲哚-2-羧酸)二甲酯的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Sep 12;71(Pt 10):1140-2. doi: 10.1107/S205698901501628X. eCollection 2015 Oct 1.
5
Crystal structure of dimethyl 3,3'-[(4-chloro-phen-yl)methyl-ene]bis-(1H-indole-2-carboxyl-ate).3,3'-[(4-氯苯基)亚甲基]双(1H-吲哚-2-羧酸)二甲酯的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Sep 27;70(Pt 10):259-61. doi: 10.1107/S1600536814020686. eCollection 2014 Oct 1.
6
Crystal structure of dimethyl 3,3'-[(3-fluoro-phenyl)methyl-ene]bis-(1H-indole-2-carboxyl-ate).3,3'-[(3-氟苯基)亚甲基]双-(1H-吲哚-2-羧酸二甲酯的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Nov 29;70(Pt 12):593-5. doi: 10.1107/S1600536814025756. eCollection 2014 Dec 1.
7
Crystal structure of diethyl 3,3'-[(2,4-di-chloro-phen-yl)methyl-idene]bis-(1-indole-2-carboxyl-ate).3,3'-[(2,4-二氯苯基)亚甲基]双(1-吲哚-2-羧酸乙酯)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Nov 3;73(Pt 12):1817-1819. doi: 10.1107/S2056989017015730. eCollection 2017 Dec 1.
8
Crystal structure of dimethyl 3,3'-[(3-nitro-phen-yl)methyl-ene]bis-(1H-indole-2-carboxyl-ate) ethanol monosolvate.3,3'-[(3-硝基苯基)亚甲基]双-(1H-吲哚-2-羧酸酯)二甲酯乙醇单溶剂合物的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Oct 24;70(Pt 11):370-2. doi: 10.1107/S1600536814022296. eCollection 2014 Nov 1.
9
Diethyl 3,3'-(phenyl-methyl-ene)bis-(1H-indole-2-carboxyl-ate).3,3'-（苯基亚甲基）双（1H-吲哚-2-羧酸）二乙酯
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2764. doi: 10.1107/S1600536812036239. Epub 2012 Aug 25.
10
Dimethyl 3,3'-(phenyl-methyl-ene)bis-(1H-indole-2-carboxyl-ate).3,3'-（苯基亚甲基）双（1H-吲哚-2-羧酸甲酯）二甲酯
Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 7;69(Pt 10):o1516. doi: 10.1107/S1600536813024471. eCollection 2013.

引用本文的文献

1
Dimethyl 3,3'-[(4-nitro-phen-yl)methyl-ene]bis-(1-indole-2-carboxyl-ate) ethanol hemisolvate.3,3'-[(4-硝基苯基)亚甲基]双(1-吲哚-2-羧酸乙酯)乙醇半溶剂合物
IUCrdata. 2021 Jan 26;6(Pt 2):x210057. doi: 10.1107/S2414314621000572. eCollection 2021 Feb.

本文引用的文献

1
Crystal structure of diethyl 3,3'-[(2-fluoro-phen-yl)methyl-idene]bis-(1-indole-2-carboxyl-ate).3,3'-[(2-氟苯基)亚甲基]双(1-吲哚-2-羧酸乙酯)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Oct 31;73(Pt 11):1790-1792. doi: 10.1107/S2056989017015523. eCollection 2017 Nov 1.
2
Crystal structure of dimethyl 3,3'-[(4-fluoro-phen-yl)methyl-ene]bis-(1H-indole-2-carboxyl-ate).3,3'-[(4-氟苯基)亚甲基]双(1H-吲哚-2-羧酸)二甲酯的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Sep 12;71(Pt 10):1140-2. doi: 10.1107/S205698901501628X. eCollection 2015 Oct 1.
3
Crystal structure of dimethyl 3,3'-[(3-fluoro-phenyl)methyl-ene]bis-(1H-indole-2-carboxyl-ate).
3,3'-[(3-氟苯基)亚甲基]双-(1H-吲哚-2-羧酸二甲酯的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Nov 29;70(Pt 12):593-5. doi: 10.1107/S1600536814025756. eCollection 2014 Dec 1.
4
Diethyl 3,3'-(phenyl-methyl-ene)bis-(1H-indole-2-carboxyl-ate).3,3'-（苯基亚甲基）双（1H-吲哚-2-羧酸）二乙酯
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2764. doi: 10.1107/S1600536812036239. Epub 2012 Aug 25.
5
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.