The College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, P. R. China.
Chem Commun (Camb). 2013 Nov 25;49(91):10697-9. doi: 10.1039/c3cc46601a.
This research provides a novel approach for introducing a CF3CH2 group onto aromatic rings using Pd(OAc)2/palladacycle as a catalyst for the Suzuki cross-coupling reaction of CF3CH2OTs (OTs = 4-methylbenzene sulfonate) with arylboronic acids.
本研究提供了一种使用 Pd(OAc)2/钯环作为催化剂,通过 Suzuki 交叉偶联反应将 CF3CH2OTs(OTs = 对甲苯磺酸酯)与芳基硼酸偶联,在芳环上引入 CF3CH2 基团的新方法。