Department of Mechanical and Process Engineering, ETH Zürich, Zürich CH-8092, Switzerland.
Chem Soc Rev. 2014 Jan 21;43(2):565-76. doi: 10.1039/c3cs60253b.
Fast transport of water inside nanoscale graphitic surfaces, namely carbon nanotubes and graphene, forms the basis of aqueous carbon nanofluidic phenomena for which there are numerous applications in energy and environmental fields. In this tutorial review, we provide the basic principles of nanofluidics using carbon materials. We also address thermodynamic and structural aspects of favourable water confinement between hydrophobic carbon surfaces. We outline the experimental and theoretical history and consider the current status of ultrafast water transport inside carbon nanotubes, together with recent applications of aqueous carbon nanofluidic phenomena for energy generation and energy storage. We briefly discuss the challenges and opportunities for utilization of fast water transport in the graphitic nanoenvironment as a means to offer a clean and sustainable source of energy technology.
水在纳米级石墨表面(即碳纳米管和石墨烯)内的快速输运是水相碳纳米流体制备的基础,在能源和环境领域有着广泛的应用。在这篇综述中,我们提供了使用碳材料的纳米流体制备的基本原理。我们还讨论了疏水碳表面之间有利的水约束的热力学和结构方面。我们概述了实验和理论历史,并考虑了超快速水在碳纳米管内输运的现状,以及水相碳纳米流体制备在能源产生和储存方面的最新应用。我们简要讨论了利用石墨纳米环境中快速输运水作为清洁能源技术的挑战和机遇。