氯化亚铜介导的[60]富勒烯与胺在二甲基丙二炔酸二甲酯存在或不存在的情况下的反应：富勒吡咯啉或氮杂环丁烷富勒烯衍生物的制备。
CuCl2-mediated reaction of [60]fullerene with amines in the presence or absence of dimethyl acetylenedicarboxylate: preparation of fulleropyrroline or aziridinofullerene derivatives.
机构信息
School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.
出版信息
J Org Chem. 2013 Dec 6;78(23):11992-8. doi: 10.1021/jo402043p. Epub 2013 Nov 8.
PMID:24147653
Abstract
The CuCl2-mediated three-component reaction of C60 with amines and dimethyl acetylenedicarboxylate afforded the fulleropyrrolines in moderate yields. Furthermore, the CuCl2-mediated oxidative [2 + 1] reaction of C60 with aromatic amines bearing a strong electron-withdrawing group provided the aziridinofullerenes and the selective cis-1-bisaziridinofullerenes.
摘要
氯化亚铜介导的 C60 与胺和二甲基丙二炔酸二甲酯的三组分反应以中等产率得到了富勒吡咯啉。此外，氯化亚铜介导的 C60 与带有强吸电子基团的芳族胺的氧化[2+1]反应提供了氮丙啶富勒烯和选择性顺式-1-双氮丙啶富勒烯。
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