CAS Key Laboratory of Soft Matter Chemistry, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, PR China.
Org Lett. 2013 Apr 5;15(7):1532-5. doi: 10.1021/ol400319w. Epub 2013 Mar 15.
The silver carbonate promoted reaction of [60]fullerene with (Z)-N-arylbenzamidines afforded the unprecedented C60-fused imidazoline derivatives in high yields. Substrates with both electron-donating and -withdrawing groups on aromatic rings could be employed. In addition, the electrochemistry and further selective functionalization of the obtained C60-fused imidazolines were investigated.
碳酸银促进[60]富勒烯与（Z）-N-芳基苯甲脒的反应，以高产率得到了前所未有的 C60 稠合的咪唑啉衍生物。芳环上具有供电子和吸电子基团的底物都可以使用。此外，还研究了所得 C60 稠合咪唑啉的电化学和进一步的选择性官能化。
