分子构造：从晶体到晶体的晶体。
Molecular tectonics: from crystals to crystals of crystals.
机构信息
Institute of Physical Chemistry, Splaiul Independentei 202, 060021, Bucharest, Romania.
出版信息
Chem Commun (Camb). 2013 Dec 11;49(95):11209-11. doi: 10.1039/c3cc45205k.
PMID:24154609
Abstract
The in situ combination of M(II) cations (Co, Ni, Cu or Zn) with 2,4,6-pyridinetricarboxylic acid as a ligand, a bisamidinium dication as a H-bond donor tecton and NaOH leads to the formation of anionic metal complexes ML2(2-) and their interconnection into isomorphous 3D H-bonded networks displaying different colours which were used as preformed seed crystals for the formation of crystals of crystals by 3D epitaxial growth.
摘要
将 M(II) 阳离子（Co、Ni、Cu 或 Zn）与 2,4,6-吡啶三羧酸作为配体原位组合，将双脒二阳离子作为 H 键给体构筑单元，与 NaOH 一起作用，生成阴离子金属配合物 ML2(2-)，并将其连接成具有不同颜色的同构 3D H 键合网络，这些网络可用作预形成的晶种，通过 3D 外延生长形成晶体。
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