分子构造：将异双金属配位网络分级组织成异三金属核壳晶体。
Molecular tectonics: hierarchical organization of heterobimetallic coordination networks into heterotrimetallic core-shell crystals.
作者信息
Zhang Fan, Adolf Cyril R R, Zigon Nicolas, Ferlay Sylvie, Kyritsakas Nathalie, Hosseini Mir Wais
机构信息
Molecular Tectonics Laboratory, UMR UdS-CNRS 7140, University of Strasbourg, Institut Le Bel, 4, rue Blaise Pascal, F-67000 Strasbourg, France.
出版信息
Chem Commun (Camb). 2017 Mar 23;53(25):3587-3590. doi: 10.1039/c7cc01455d.
Combinations of a neutral Pt(ii) organometallic tecton bearing two triphenylphosphine and two 3-ethynylpyridyl coordinating moieties in trans positions with MX complexes (M = Co(ii) and X = Cl or Br and M = Zn(ii) and X = Cl) lead to the formation of isostructural 1D heterobimetallic coordination compounds. By 3D epitaxial growth processes, using coordination bonding, heterotrimetallic core-shell crystals are generated by the growth of crystalline layers on seed crystals.
一种在反位带有两个三苯基膦和两个3-乙炔基吡啶配位基团的中性Pt(ii)有机金属结构基元与MX配合物（M = Co(ii)且X = Cl或Br以及M = Zn(ii)且X = Cl）的组合会导致形成同构的一维异双金属配位化合物。通过三维外延生长过程，利用配位键，通过在籽晶上生长晶体层生成异三金属核壳晶体。
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