α-异育亨宾碱，β-异育亨宾碱的对映体互补催化剂。
α-Isocupreine, an enantiocomplementary catalyst of β-isocupreidine.
出版信息
Chemistry. 2013 Sep 16;19(38):12653-6. doi: 10.1002/chem.201302665.
PMID:24175342
Abstract
Complementary chemistry! α-Isocupreine (-ICPN) was synthesized for the first time in one step from quinine by treatment with CF3SO3H (see scheme). This compound serves as an enantiocomplementary catalyst to β-isocupreidine (β-ICD) in the Morita–Baylis–Hillman reaction.
摘要
互补化学！α-异铜叶精（-ICPN）首次由奎宁经 CF3SO3H 一步合成得到（见方案）。该化合物在 Morita–Baylis–Hillman 反应中作为 β-异铜叶精（β-ICD）的对映体互补催化剂。
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