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六方中空微管负载 Bi2S3 量子点用于催化降解染料。

Hexagonal hollow microtubes incorporated Bi2S3-quantum-dots for catalytic degradation of dyes.

机构信息

Key Laboratory for Colloid and Interface Chemistry & Key Laboratory of Special Aggregated Materials (Shandong University), Ministry of Education, Jinan 250100, China.

出版信息

J Colloid Interface Sci. 2014 Jan 1;413:133-9. doi: 10.1016/j.jcis.2013.09.021. Epub 2013 Sep 29.

Abstract

In this paper, hexagonal hollow microtubes were easily produced through a thermal annealing process from the mixtures in aqueous solution of cholic acid (CA) and a zwitterionic surfactant tetradecyldimethylamine oxide (C14DMAO). The walls of the microtubes can solubilize rhodamine 6G and fluorescein, showing excellent fluorescence properties. The microtubes incorporated Bi2S3 quantum dots also show excellent fluorescence property and catalytic performance for degradation of dye pollutants. The microtubes incorporated Bi2S3 quantum dots can be used recycles. Typically, after recycling eight times, the degradation percentage of the dye pollutants can reach 77%. This opens a tried-and-true avenue for producing powerful nano- and microtube materials based on combinations of surfactants and convenient self-assembly strategies and can be applied in catalytic degradation of dyes-containing wastewater.

摘要

本文通过在胆酸(CA)和两性离子表面活性剂十四烷基二甲基氧化胺(C14DMAO)的水溶液混合物中进行热退火处理,轻松制备出了六方中空微管。微管的壁体能溶解罗丹明 6G 和荧光素,表现出优异的荧光性能。负载 Bi2S3 量子点的微管也表现出优异的荧光性能和对染料污染物的催化降解性能。负载 Bi2S3 量子点的微管可回收利用。通常,经过 8 次回收后,染料污染物的降解率可达到 77%。这为基于表面活性剂和方便的自组装策略的组合生产功能强大的纳米和微管材料开辟了一条可行的途径,并可应用于含染料废水的催化降解。

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