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利用生物合成的银纳米粒子催化降解有机染料。

Catalytic degradation of organic dyes using biosynthesized silver nanoparticles.

机构信息

Department of Physics, Mar Ivanios College, Thiruvananthapuram 695 015, India.

出版信息

Micron. 2014 Jan;56:54-62. doi: 10.1016/j.micron.2013.10.006. Epub 2013 Oct 19.

DOI:10.1016/j.micron.2013.10.006
PMID:24210247
Abstract

The green synthesis of metallic nanoparticles paved the way to improve and protect the environment by decreasing the use of toxic chemicals and eliminating biological risks in biomedical applications. Plant mediated synthesis of metal nanoparticles is gaining more importance owing to its simplicity, rapid rate of synthesis of nanoparticles and eco-friendliness. The present article reports an environmentally benign and unexploited method for the synthesis of silver nanocatalysts using Trigonella foenum-graecum seeds, which is a potential source of phytochemicals. The UV-visible absorption spectra of the silver samples exhibited distinct band centered around 400-440 nm. The major phytochemicals present in the seed extract responsible for the formation of silver nanocatalysts are identified using FTIR spectroscopy. The report emphasizes the effect of the size of silver nanoparticles on the degradation rate of hazardous dyes, methyl orange, methylene blue and eosin Y by NaBH4. The efficiency of silver nanoparticles as a promising candidate for the catalysis of organic dyes by NaBH4 through the electron transfer process is established in the present study.

摘要

金属纳米粒子的绿色合成方法通过减少有毒化学物质的使用和消除生物医学应用中的生物风险,为改善和保护环境铺平了道路。由于植物介导的金属纳米粒子合成具有简单、快速的纳米粒子合成速度和生态友好性,因此越来越受到重视。本文报道了一种使用 Trigonella foenum-graecum 种子合成银纳米催化剂的环保且未开发的方法,Trigonella foenum-graecum 种子是植物化学物质的潜在来源。银样品的紫外-可见吸收光谱显示出中心位于 400-440nm 左右的明显带。使用傅里叶变换红外光谱法确定了种子提取物中负责形成银纳米催化剂的主要植物化学物质。该报告强调了银纳米粒子的尺寸对 NaBH4 降解危险染料(如甲基橙、亚甲蓝和曙红 Y)的速率的影响。本研究通过电子转移过程建立了银纳米粒子作为 NaBH4 催化有机染料的有前途的候选物的效率。

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