Fachbereich Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger-Straße Geb. 52, D-67663 Kaiserslautern, Germany.
Chem Soc Rev. 2014 Feb 7;43(3):901-10. doi: 10.1039/c3cs60318k.
Towards "Oxidative-Ullmann-Goldberg" and "Oxidative-Buchwald-Hartwig" type amination reactions. This review focuses on the newly developed oxidative C-N bond formation techniques, applicable in the field of organic synthesis. Particular emphasis is given to those which are classified as cross-dehydrogenative-couplings, through dual C-H and N-H activation, thus formally extruding "H2" as a by-product.
迈向“氧化-Ullmann-Goldberg”和“氧化-Buchwald-Hartwig”型胺化反应。本综述重点介绍了新开发的适用于有机合成领域的氧化 C-N 键形成技术。特别强调那些通过双重 C-H 和 N-H 活化被归类为交叉脱氢偶联的反应，从而正式将“H2”作为副产物挤出。
