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软玻璃态流变学模型的非平衡热力学

Nonequilibrium thermodynamics of the soft glassy rheology model.

作者信息

Fuereder Ingo, Ilg Patrick

机构信息

ETH Zurich, Department of Materials, Wolfgang-Pauli-Str. 10, CH-8093 Zurich, Switzerland.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2013 Oct;88(4):042134. doi: 10.1103/PhysRevE.88.042134. Epub 2013 Oct 22.

Abstract

The soft glassy rheology (SGR) model is a mesoscopic framework which proved to be very successful in describing flow and deformation of various amorphous materials phenomenologically (e.g., pastes, slurries, foams, etc.). In this paper, we cast SGR in a general, model-independent framework for nonequilibrium thermodynamics called general equation for the nonequilibrium reversible-irreversible coupling. This leads to a formulation of SGR which clarifies how it can properly be coupled to hydrodynamic fields, resulting in a thermodynamically consistent, local, continuum version of SGR. Additionally, we find that compliance with thermodynamics imposes the existence of a modification to the stress tensor as predicted by SGR.

摘要

软玻璃态流变学(SGR)模型是一个细观框架,事实证明它在唯象地描述各种非晶态材料(如糊剂、浆料、泡沫等)的流动和变形方面非常成功。在本文中,我们将SGR置于一个称为非平衡可逆-不可逆耦合通用方程的非平衡热力学通用的、与模型无关的框架中。这导致了SGR的一种表述,阐明了它如何能够恰当地与流体动力学场耦合,从而得到一个热力学一致的、局部的、连续介质版本的SGR。此外,我们发现,遵循热力学要求对SGR预测的应力张量进行修正。

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